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(iii) Ethyl alcohol A:An acid dissociation constant, Ka is the equilibrium constant for a chemical reaction, basically the, Q:Show, using equations for each, how according to the Bronsted-Lowry theory, the hydrogen sulfate, A:Given, Q:In a 0.35Msolution, a weak acid is 2.8% dissociated. Arrhenius theory Question = Is SiCl2F2polar or nonpolar ? A solution is a mixture of two or more substances, so it can be either acidic or basic. pH is basic (>7), LiNO3 which comes from a strong base (LiOH) and a strong acid (HNO3). Reset Hel SrCl2 SICH ABE: NIHF CHANENONACHO. Recommended textbook solutions. This means that when calculating the values for Kb of CO32-, the Kb of the first hydrolysis reaction will be \(K_{b1} = \dfrac{K_w}{K_{a2}}\) since it will go in the reverse order. Polar "In chemistry, polarity i An acid is a molecule or ion capable of donating a, In chemistry, bases are substances that, in aqueous solution, are slippery to the touch, taste astringent, change the color of. If the solution is acidic, the strip will turn red or pink. If it turns blue, the salt is basic. HA(aq)+. There are several guiding principles that summarize the outcome: Do not be intimidated by the salts of polyprotic acids. NH4Cl-acidic. See Answer Question: Determine if the solution formed by each salt is acidic, basic, or neutral. Licio h. CsCN Determine whether the following mixtures would form a buffer; and if so, what is the approximate pH? This problem has been solved! The base is, Q:Consider the base hydroxylamine, NH2OH. The word "neutral" is sometimes added to "ammonium fluoride" to represent the neutral salt[NH 4]F vs. the "acid salt" (NH 4 HF 2). Ionic equilibri. Because this reaction produces OH-, the resulting solution will be basic and cause a pH>7. New Questions About Fantasy Football Symbols Answered and Why You Must Read Every Word of This Report. Explain how you arrived at your answer. BASE ( wikipedia) To make coconut puree, start by removing the meat from a fresh coconut. How does the strength of a conjugate base depend on these factors? What is the final pH of a solution that has 0.123M of NH4F? NHs Is A Conjugate Of A Weak Base A Acid. The solution should be slightly acidic. Give an example of such an oxide. HF dissociates equally well in a solution of KCl and in pure water. Question = Is C2H6Opolar or nonpolar ? Then, slowly add the salt solution to the container while stirring. Kardea Brown husband is Devarsh Varsani. How to calculate the pH of an acetic acid/ calcium acetate buffer? Hickory is a strong, durable wood that, Read More Is Hickory Good for Cutting Boards?Continue, The answer to this question is a resounding yes! 15K views 2 years ago To tell if NH4I (Ammonium iodide) forms an acidic, basic (alkaline), or neutral solution we can use these three simple rules along with the neutralization reaction. acidic. \[\dfrac{x^2}{0.2-x}=\dfrac{1*10^-14}{3.98 \times 10{-13}}\]. Question = Is SCl6polar or nonpolar ? Petrucci, Ralph H., William S. Harwood, F G. Herring, and Jeffry D. Madura. 1 mole of HCN reacts with 1 mole of NaOH, Q:Consider the following three compounds: propane, BBr3, and H2S. The ionization, Q:Hygrogen cyanide gas (HCN), a power respiratotoxic, inhibitor, is highly toxic. c . If pH > 7, then the solution is basic. The "parent" base is KOH (a strong base), and the "parent" acid is HCl (a strong acid). Determine if the solution formed by each salt is acidic, basic, or neutral. A 0.47M aqueous solution of butylamine has a ph of 12.13. Required fields are marked *. It's not clear to me what straightforward notation, according to my screen, gets retranslated to a different format. b), A:Hydrolysis of salt produces acid and base. Is an aqueous solution of CH3NH C2H302 acidic, basic or neutral? Cotton candy is a type of confectionery that is made from sugar. Solution containing salt of strong acid and strong base is neural. b). Is there a way that I can see the wrong view before I post it? A:Acids are the species that produces hydronium ions in aqueous solution. What type of solution forms when a metal oxide dissolves in water? + 20 For unlimited access to Homework Help, a Homework+ subscription is required. To test with litmus paper, wet the paper with the salt solution and then compare the color of the paper to the chart included with the litmus kit. -A glass or plastic container water, A:According to Arrhenius , an acid is defined as any species that gives H+ ions in water . To start, add a small amount of the phenol red indicator solution to your container. Dissociation equilibria of ammonium bifluoride in water, We've added a "Necessary cookies only" option to the cookie consent popup. HF is stronger acid than NH4+, is not it ? Given, If it turns blue, the salt is basic. If the paper turns red, the salt is acidic. The best answers are voted up and rise to the top, Not the answer you're looking for? However, some common methods include using litmus paper or an indicator solution. They are also said to be a good source of energy, Read More Are Zone Bars Gluten Free?Continue, Your email address will not be published. Basic b. Alkaline c. Both d. Neither. Question = Is C2Cl2polar or nonpolar ? NaF-basic. A, Q:Coleiro-ic Acid, HColeiro , is a new organic compound used to manufacture hypnotic drugs and some, Q:1. C5H5NClO4 is acidic, basic or neutral? Ka for NH4+ is 1.00 x 10^-14 / 1.8 x 10^-5 = 5.6 x 10^-10. Explain why? You'll get a detailed solution from a subject matter expert that helps you learn core concepts. \(NH^+ _{4(aq)} + H_2O {(l)} \rightleftharpoons NH_{3(aq)} + H_3O_{(aq)}\), \(PO^3-_{4(aq)} + H_2O_{(l)} \rightleftharpoons HPO^{2-}_{4(aq)} + OH^-_{(aq)}\). Does ZnSO4 + H2 at high pressure reverses to Zn + H2SO4? The color chart that comes with the indicator will show you whether the solution is acidic, basic, or neutral. Question = Is if4+polar or nonpolar ? NHs is a conjugate of a weak base a acid. What video game is Charlie playing in Poker Face S01E07? [6], Except where otherwise noted, data are given for materials in their, "Fluoride Toxicity - an overview | ScienceDirect Topics", https://en.wikipedia.org/w/index.php?title=Ammonium_fluoride&oldid=1096316729, slightly soluble in alcohol, insoluble in liquid ammonia, This page was last edited on 3 July 2022, at 18:03. Acid or base or, Q:a) Is an aqueous solution that is 0.10 M Na2S (aq) likely to be acidic, basic or pH neutral?, Q:The pHpH of a 1.00 MM solution of caffeine, a weak organic base, is 12.300. Posted 11 months ago Recent Questions in Software Engineering Q: This reaction produces a hydronium ion, making the solution acidic, lowering the pH below 7. Read More Who is Kardea Brown Husband?Continue, Hickory is a very popular wood for cutting boards because it is extremely hard and durable. Save my name, email, and website in this browser for the next time I comment. https://www.thinglink.com/scene/636594447202648065 ACID ( wikipedia) An acid is a molecule or ion capable of donating a hydron (proton or hydrogen ion H+), or, alternatively, capable of forming a covalent bond with an electron pair (a Lewis acid). Medium. KBr For oxyacids, how does acid strength depend on a. the strength of the bond to the acidic hydrogen atom? These salts' solutions also, Q:The pH of five unknown solutions, V, W, X, Y, and Z are 12, 4, 7, 9 and (a) [ OH ]=0.1M(b) [ OH ]=[ Ba2+ ](c) pH=13.30(d) [ H+ ]=11 0 7 M. Suppose you have 557 mL of 0.0300 M HCl, and you want to make up a solution of HCl that has a pH of 1.751. Indicate whether the solutions in Parts A and B are acidic or basic. Q:Which of the following has the highest acidity: pH 1, pH 5, or pH 9? NaCl,KBr solutions are neutral, NaCN, NaNO 2 and KF solutions are basic and NH 4NO 3 solution is acidic. Identify each reactant as either a Lewis acid or a Lewis base. Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste. CaCl2 c. the number of oxygen atoms? Another way to test for acids and bases is with indicators. Now, NO3- won't attract an H+ because it is usually from a strong acid. BCl3 Kardea Brown husband is a lucky man! This substance is commonly called "commercial ammonium fluoride". For those who are not familiar with Zone Bars, they are a type of protein bar that is marketed as being beneficial for weight loss and body composition. HF + H2O ------> H+(aq) + F-(aq) Is calcium oxide an ionic or covalent bond . The easiest way to tell is to look at each salt and determine how it was made, i.e. Zone Bars are in fact gluten free. (Hint: The H,0* due to the water, Q:a basic solution contains 0.0004 M hydroxide ions. In chemistry, a salt is an ionic compound that can be formed by the neutralization reaction of an acid and a base. Coal and other fossil fuels usually contain sulfur compounds that produce sulfur dioxide, SO2, when burned. [OH-] =? The concept of the $\ce{HF2-}$ moiety dominating the discussion for a solution is probably making the analysis murkier than it needs to be. There is no one definitive way to test whether a salt is acidic or basic. Same when it asks for lowest pH. If the paper turns red, the salt is acidic. - all of, A:According Arrhenius base is define when substance dissolved aqueous solution it's release OH- ions. Giving reasons, predict whether the aqueous solutions of the following compounds are According to the question - What sort of strategies would a medieval military use against a fantasy giant? Write reactions to justify your answers. GIven: pKb NH3=4.75. It acts as a base, accepting a proton from water. To test with an indicator solution, add a few drops of indicator to the salt solution and observe the color change. Q:How is the magnitude of Ka related to acid strength ? Combine the solutions and the $\mathrm{pH}$ will settle out somewhere between $1$ and $7,$ because of the common ion effect: $\ce{F-}$ from the $\ce{NH4F}$ inhibits the ionization of $\ce{HF},$ but the solution is still acidic. NH4F + H2O ------>. It is recommended that NaHnot be used with polar aprotic solvents at all. Therefore the acid strength here is slightly higher than the base strength. NH4F is a salt of weak acid HF (Ka = 7.2 104) and weak base NH4OH (Kb = 1.8 105), the solution of NH4F will be slightly acidic. My role is to promote a culture of safety at Homewood by working with faculty, staff, and students to bring safety expertise into the laboratory. The pH scale goes from 0-14, with 7 being neutral, below 7 being acidic and above 7 being basic. Why is the solution of ammonium bifluoride more acidic than aqueous ammonium fluoride? Assume, A:Strongest base: CH3NH2Middle base: NaCN, Weakest base: NaCl, Q:Chlorobenzene, C6H5Cl, is a key intermediate in the manufacture of dyes and pesticides. Join / Login >> Class 11 >> Chemistry . Christopher Wu (UCD), Christian Dowell (UCD), Nicole Hooper (UCD). It is a very weak, A:HCN reacts with NaOH as follows: Question: Is B2 2-a Paramagnetic or Diamagnetic ? \(NaOCl _{(s)} \rightarrow Na^+_{(aq)} + OCl^-_{(aq)}\). Weak acids can be neutralized by strong bases to form water and salts. Will NH4F be acidic, basic or neutral in water? Other ion = Cl- HCN+NaOHNaCN+H2O (iv) NH4OH, Q:4 The extent of, Q:What is the pH of a 1.8x10 molar aqueous nitric acid solution? So The PH Is Determined By Their Ka Value. HONH3. Salt solution Kardea is a incredible woman who always puts her family first. (For polyatomic species, consider the Lewis acid behaviour. Base are the compounds that accept protons. It's still just a salt. $\pu{0.1 M});$ you get a $\mathrm{pH}\approx 1$. NH4F-acidic. 0 0 Find All solutions for this book Chemistry Part-I NCERT Acid-base indicators are solutions that change color in the presence of an acid or base. Consider adding $\ce{NH4F}$ to water: you get a $\mathrm{pH}$ near $7.$ In a separate container, add $\ce{HF}$ to water (approx. [H+]=4.01104Mb. Salt. JHU Department of Health, Safety & Environment, https://cen.acs.org/safety/lab-safety/Chemists-continue-forget-safety-concerns-about-sodium-hydride/97/web/2019/08. We reviewed their content and use your feedback to keep the quality high. It is made, A:The species which are electron rich and hence,have the capability to donate the electrons are known. NH4 Ka 5.6x10-10 The Acid Is Stronger Than The Base, So The Solution Will Be Slightly Acidic. Well, there are, No, cotton candy does not have dairy. First, use litmus paper to test the pH of the salt solution. Answer: B2 2-is a Diamagnetic What is Paramagnetic and Diamagnetic ? How to tell which packages are held back due to phased updates. This property is shared among all . The gastric juices in my stomach have a pH between 1 and 2. Answers A - C General Chemistry: Principles and Modern Applications. A link to the app was sent to your phone. What can we say about their pH? Solution for Determine whether aqueous solutions of the following salts are acidic, basic, or neutral: (a) KBr (b) NaHCO3 (c) NH4Cl (d) Na2HPO4 (e) NH4F Also, It changes color in, Q:Except for the Na spectator ion, aqueous solutions of CHCOOH and CHCOONa contain the same, A:Weak acid dissociates partially in an aqueous solution to furnish the hydrogen ions. a. Q:Determine whether solutions of the following salts are acidic, basic, or neutral at 25oC: (a), A:Given : Need help with something else? If the acidic part is more strong then, the solution will, Q:Which of the following does NOT describe Arrhenius acids and bases? I found for NH4F to be acidic by finding Ka (NH3) being greater than Kb (HF). 35,000 worksheets, games, and lesson plans, Spanish-English dictionary, translator, and learning, a Question Determine whether aqueous solutions of the following salts are acidic, basic, or neutral: (a) KBr (b) NaHCO3 (c) NH4Cl (d) Na2HPO4 (e) NH4F. NH4 Ka 5.6x10-10 The acid is stronger than the base, so the solution will be slightly acidic. Upvote 0 Downvote. It is is salt of weak base (Al(OH)3), Q:Chlorobenzene, CHCl, is a key intermediate in the manu-facture of dyes and pesticides. Calculate [OH2]. Calculate theKaKaof, A:In this question, we have to find the pH of solution by the use of Henderson hessalbalch equation,, Q:The following diagrams represent aqueous solutions ofthree acids, HX, HY, and HZ. To complete the other steps, follow the same manner of this calculation. d). Second, you can use a universal indicator to test the pH of the salt solution. pH is neutral (7), KCN which comes from a strong base (KOH) and a weak acid (HCN). 22. Determine whether solutions of the following salts are acidic, basic, or neutralat 25oC:. In the sublimation, the salt decomposes to ammonia and hydrogen fluoride, and the two gases can recombine to give ammonium fluoride, i.e. If the solid ammonium fluoride (NH4F) is dissolved in pure water, will the resulting solution be acidic, basic, or neutral? Why did Ukraine abstain from the UNHRC vote on China? To tell if NH4I (Ammonium iodide) forms an acidic, basic (alkaline), or neutral solution we can use these three simple rules along with the neutralization reaction that formed NH4I .First we need to figure out the acid and base that were neutralized to form Ammonium iodide. Is it correct to use "the" before "materials used in making buildings are"? The water, A:a) Since the acid which will dissociate more will be more stronger acid View this solution and millions of others when you join today! It is also used for preserving wood, as a mothproofing agent, in printing and dyeing textiles, and as an antiseptic in breweries. Note: For NH3, Kb = 1.8 10-5; for HF, Ka = 7.2 10-4. The solution containing a salt of strong acid and weak base is acidic. Acid/Base dissociation constants relationship, Basic behaviour of bromide ion with sulfuric and phosphonic acid, AC Op-amp integrator with DC Gain Control in LTspice. Round your answer to 2 decimal, A:pH of the solution is the measure of Hydrogen ion concentration which determines the strength of, Q:When in contact with a natural indicator (dried eggplant peelings), what color should the following, A:Egg plant peel indicator contains anthocyanins. Laboratory Safety Advocate for the Johns Hopkins University Homewood Campus. HC7H5O2. Where does this (supposedly) Gibson quote come from? (a) Calculate the[H3O+], pH, [OH]and. See https://cen.acs.org/safety/lab-safety/Chemists-continue-forget-safety-concerns-about-sodium-hydride/97/web/2019/08 for more detail. KaHF=6.6*10^-4. However, NH4+ will lose an electron and act as an acid (NH4+ is the conjugate acid of NH3) by the following reaction: \[NH^+_{4(aq)} + H_2O_{(l)} \rightleftharpoons NH_{3(aq)} + H_3O^+_{(aq)}\]. In this section of chemistry, we discuss the pH values of salts based on several conditions. B. strongly acidic. O a. The word "neutral" is sometimes added to "ammonium fluoride" to represent the neutral salt[NH4]F vs. the "acid salt" (NH4HF2). Learn more about Stack Overflow the company, and our products. Kb for NO2- is 1.00 x 10^-14 / 4.5 x 10^-4 = 2.2 x 10^-11. It also has a beautiful grain pattern that can add a unique look to your kitchen. 2003-2023 Chegg Inc. All rights reserved. What percentage of the amine is protonated if the pH of a, A:Assuming the amine is B. from which acid and which base. Is Milk of Magnesia acidic, basic, or neutral? The acid salt is usually used in preference to the neutral salt in the etching of glass and related silicates. KI-neutral. J.R. S. Determine whether aqueous solutions of the following salts are acidic, basic, or neutral: (a) KBr (b) NaHCO3 (c) NH4Cl (d) Na2HPO4 (e) NH4F Also, how would I know what the products are for these reactions. Get access to millions of step-by-step textbook and homework solutions, Send experts your homework questions or start a chat with a tutor, Check for plagiarism and create citations in seconds, Get instant explanations to difficult math equations, Chemical equilibrium and ionic equilibrium are two major concepts in chemistry. I have already been notified about certain subscripts, but not the temperature. A:To calculate, we would use the given information . If you want to know whether a salt is acidic or basic, there are a few simple tests you can perform. HS. Na2SO4 The easiest way to tell if a solution is acidic or basic is by using a pH indicator strip. Question: Is calcium oxidean ionic or covalent bond ? (K (NH3) = 1.76 x 10-5, Ka (HF) = 6.8 x 10-4) Drag the appropriate items to their respective bins. To do this test, you will need: This property is shared among all soluble fluorides. Rebecca Tefera 2:45pm An aqueous solution of NH4F is acidic. First week only $4.99! Do I need a thermal expansion tank if I already have a pressure tank? Is the solution neutral, acidic, or basic? Question: Determine whether the following salts would create an acidic, basic, or neutral solution. The same way that polyprotic acids lose H. Predict whether the pH of each of the following salts placed into water is acidic, basic, or neutral. Browse other questions tagged, Start here for a quick overview of the site, Detailed answers to any questions you might have, Discuss the workings and policies of this site. D. weakly basic. A, A:Buffer solution is defined as the aqueous solution which consists of a weak base/acid and its, Q:7 (a) Describe what happens when each of the following molecules is [H3O+] = 8.87109M, Q:Which of the following can be classified as an Arrhenius base?
NH4 Ka 5.610-10 The acid is stronger than the base, so the solution will be slightly acidic. Based on how strong the ion acts as an acid or base, it will produce varying pH levels. Answer = C2Cl2 is Polar What is polarand non-polar? So only the first step will be completed here. Enjoy your, Read More How to Make Coconut Puree?Continue, Maui is so brown because it is an island with a lot of volcanic activity. Did this satellite streak past the Hubble Space Telescope so close that it was out of focus? They have been married since June 2019 and have a daughter named Skylar. whether an aqueous solution of, A:Given salts are :- Arrhenius acid act as a good electrolyte as it dissociates to its respective ions in the aqueous solutions. Minimising the environmental effects of my dyson brain. If the salt comes from a STRONG acid and weak base, the pH will be acidic (<7) If the salt comes from s STRONG base and a weak acid, the pH will be basic (>7) For example, red cabbage juice can be used as an indicator because it changes color from purple to pink in the presence of an acid and changes color from purple to green in the presence of a base. To learn more, see our tips on writing great answers. Basic c. Neutral. First of all, we know a few things: Take for example dissociation of \(\ce{H2CO3}\), carbonic acid. HSO 4-, the conjugate base of the strong acid, H 2 SO 4, is an exception. San Francisco: Pearson Education, 2007. Na+ is excluded from this reaction since it is a spectator ion. (b) When it, A:(a) Accessibility StatementFor more information contact us atinfo@libretexts.orgor check out our status page at https://status.libretexts.org. Answer = C2H6O is Polar What is polarand non-polar? You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Your email address will not be published. These strips will change color depending on the acidity or basicity of the solution. Solution Z has a pH 6 times as large as solution R. Solution Q has [OH-] half as high as that of solution Z. The answers to these questions can be found in the attached files section at the bottom of the page. Yes, they're bigger and "badder" then most other salts. ), A:Solution - The way to tell if salt is acidic or not is by using the pH scale. So The PH Is Determined By Their Ka Value. My code is GPL licensed, can I issue a license to have my code be distributed in a specific MIT licensed project? One last point - the statement should be "sodium sulfate a neutral salt in aqueous solution. One way is to use litmus paper. Use MathJax to format equations. Your question is solved by a Subject Matter Expert. This is because stronger, Q:Butylamine, C4H9NH2, is a weak base. KCN acidic,, A:Given aqueous solutions Step 1: Why is that? What is the conjugate acid of NO2? Second, you can use a universal indicator to test the pH of the salt solution. a) slightly acidic b) slightly basic c) strongly basic d) neutral vi) The theory which explain amphoteric nature of water is a) Arrhenius theory b) Lewis theory SC. Bronsted-Lowry base in inorganic chemistry is any chemical substance that can accept a proton from the other chemical substance it is reacting with. Although these hazards have been known for fifty years, it appears that use of NaH with these solvents is common, judging from the large number of published syntheses that use them together. Such salts do not hydrolyze. a) KCI Reset Hel SrCl2 SICH ABE: NIHF CHANENONACHO. If pH = 7, then the solution is neutral. One possible way to remove the sulfur dioxide is to pass the combustion gases into a tower packed with calcium oxide, CaO. Na2CO3 A:Lewis acid: What type of solution forms when a nonmetal oxide dissolves in water? Aluminium has 6 electrons in its valence shell, and, Q:Predict ionization of the following drug as a function of pH. C. strongly basic. Keeping it similar to the general acid properties, Arrhenius acid also neutralizes bases and turns litmus paper into red. Will NH4F be acidic, basic or neutral in water? NH4 Ka 5.6x10-10 The Acid Is Stronger Than The. If an acid completely. GIven: pKb NH3=4.75. Get a free answer to a quick problem. Answer = if4+ isPolar What is polarand non-polar? Calculate the [OH-] in each of the following solutions. If you want a thinner consistency, add some water to the mixture and blend again. An article in the American Chemical SocietysChemical & Engineering News newsmagazine draws attention to the hazard posed by sodium hydride when used in certain polar aprotic solvents such as dimethylsulfoxide (DMSO) and dimethylformamide (DMF). No packages or subscriptions, pay only for the time you need. Label equations as what are the acid, Q:An aqueous solution at 25 C has a pOH of 6.85, Calculate the pH. NHs is a conjugate of a weak base a acid. However, hickory can be difficult to work with and is not the best choice for beginners. Amphiprotic substance = HSO4- (aq) Science Chemistry Determine if the solution formed by each salt is acidic, basic, or neutral. Salts are composed of related numbers of cations (positively charged ions) and anions (negative ions) so that the product is electrically neutral (without a net charge). \(OCl^-_{(aq)} + H_2O_{(l)} \rightleftharpoons HOCl_{(aq)} + OH^-_{(aq)}\). . Rebecca Tefera 2:45pm An aqueous solution of NH4F is acidic. I found for NH4 OneClass 12.3K subscribers Subscribe 2.7K views 2 years ago To book a personalized. (c) Classify each solution as acidic, basic, or neutral. (a) SrCl2 (b) AlBr3 (c) CH3NH3NO3 (d) NaCHO2 (e) NH4F Determine if the solution formed by each salt is acidic, basic, or neutral. Consider 0.25 M solutions of the following salts: NaCl. H2S H2NNH3NO3. a). Question = Is SbCl5 ( Antimony pentachloride ) polar or nonpolar ? Any combination of these anions and cations will produce neutral solutions. The traditional method of making cotton candy involves spinning sugar, Read More Does Cotton Candy Have Dairy?Continue. Legal. Acetic acid, HC2H3O2 hydrochloric acid (HCl) only Calculate the pH of a solution in which [H3O+]=9.5109M. The LibreTexts libraries arePowered by NICE CXone Expertand are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. { Aqueous_Solutions_Of_Salts : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.
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